Carb loading is a way of boosting endurance when exercising for longer than two hours. As Tim will be running for at least 4 hours, he thought it would be useful.
There are conflicting views about carb loading. This article gives the science behind it: basically, the body can only store a limited amount of carbohydrate, so carbohydrate loading trains the body to store the carbohydrate in the muscles and liver.
In the first part of the week, carbs are limited, and protein is high. As the week progresses, more and more of the meals are made up of carbohydrates, up to 75% in the final three days before the race. This is supposed to give optimum performance.
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